The hydrogenation of an unsaturated organic is to be carried out in a trickle bed reactor packed with 0.4-cm-diameter spherical catalyst particles. | ||
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The reaction in the pellet is first-order in both hydrogen and the organic. Hydrogen and nitrogen are fed in equimolar portions at a total pressure of 2 atm. The reactor diameter is to be 1.0 m. It is proposed to operate at a superficial liquid mass velocity of 5 kg/m 2s and a total gas flow rate of 36 mol/s. As a first approximation assume that the concentration of organic is constant and the pseudo-first-order specific reaction rate is 2.5 x 10 -5 m 3 /kg cat.s at 400 K. (a) Calculate the catalyst weight necessary to achieve 55%
conversion of the hydrogen. |
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Additional information: Liquid viscosity: 3.1 cP = 0.0031 kg/ms Liquid density: 700 kg/m 3 Hydrogen liquid diffusivity in oil: 7.0 x 10 -9 m 2 /s Organic diffusivity in organic product: 2.5 x 10 -9 m 2 /s Molecular weight of organic: 256 Daltons Hydrogen solubility: 0.004 kmol/m 3atm Pellet porosity: 0.45 Pellet density: 1600 kg/m 3 Bed porosity: 0.4 Superficial gas velocity (kg/m 2 s): 0.75 0.5 0.1 Pressure drop (kPa/m): 70 50 20 [From AIChE J., 29, 1 (1983)] |
[2rd Ed. P12-7]