Elements of
Chemical Reaction Engineering
6th Edition



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Essentials of
Chemical Reaction Engineering
Second Edition

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Chapter 15: Diffusion and Reaction in Porous Catalysts

Professional Reference Shelf

Example CD12-6: Effect of Particle Size on Catalyst Weight--Slow Reaction

     
       
    Suppose that you are operating at five times the minimum fluidization velocity, uo = 5 What would be the effect of doubling the particle diameter on the catalyst weight for the same throughput and conversion?  
       
    Solution  
       
    Substitution for u0 into Equation (CD12-89) gives  
       
     

image 12eq209.gif

(CDE12-7.1)




(CDE12-7.2)
       
    Since the temperature remains constant and there are no inter- and intraparticle resistances, kcat1 = kcat2 , the throughput (u01 = u02 ) and conversion (X1 =X 2 ) are the same for cases 1 and 2. The ratio of Equations (CDE12-7.1) and (CDE12-7.2) yields  
       
   

image 12eq210.gif

(CDE12-7.3)
       
    Recalling Equation (CD12-25) gives  
       
   

image 12eq211.gif

(CDE12-7.4)
       
    and neglecting the dependence of on dp, we see that the only parameters that vary between case 1 (dp ) and case 2 (dp2= 2dp1 ) are and W. Taking the ratio of 2to 1 and substituting for d p2 in terms of dp1 , we obtain  
       
   

(CDE12-7.5)
       
    and therefore  
       
   

image 12eq213.gif

(CDE12-7.6)
       
    Thus in the situation we have postulated, with a first-order reaction and reaction limiting the bed behavior, doubling the particle size will reduce the catalyst by approximately 75% and still maintain the same conversion.