Oxidation Studies of Propylene on the Pt(111) Surface in Reactive Conditions
Outline
Motivation
Experimental
Propylene Disproportionation in Vacuum
Propylene Oxidaiton with Coadsorbed Oxygen
Mechanism in UHV
FYNES
Propylene on Pt(111) Normal FYNES Spectra
In-Situ Stoichiometry and Bonding For Adsorbed Species
In situ Stoichiometry
FYNES of Propylene
FYNES of Propylidyne
FYNES of Oxidation Intermediate
Oxidation Mechanism
Temperature-Programmed In-Situ Catalytic Experiments
Stoichiometry of Surface Species Under Reactive Conditions
In-Situ Spectroscopy of Surface Species at 200 K
Comparison of Intermediate Spectra to Propyne Spectra
In-Situ Catalytic Studies Summary
PPT Slide
Email: gabelnic@umich.edu