Chapter 3 Self Test

Activation Energies

 

Consider the following elementary reactions

 

1)�� Which reaction has the higher activation energy?

Solution

2)�� Which reactions have the same activation energy?

Solution

3)�� Which reaction is virtually temperature insensitive?

Solution

4)�� Which reaction will dominate (i.e. take place the fastest) at high temperatures if all reactions were to take place in the same reactor?

Solution

5)�� Which reaction will dominate (take place the fastest) at moderate temperatures?

Solution

6)�� Which reaction will take place the fastest at low temperatures?

Solution

7)�� Which reactions will have the same rate of reaction at a given temperature?

Solution




































Solutions

Consider the following elementary reactions

1)�� Which reaction has the higher activation energy?

Ans. (3)

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2)�� Which reactions have the same activation energy?


Ans. (1) and (2) � Slope (�E/R) is the same.


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3)�� Which reaction is virtually temperature insensitive?


Ans. (4). k4 does not vary with temperature E4 = 0.


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4)�� Which reaction will dominate (i.e. take place the fastest) at high temperatures?



At high temperatures (1/T) is small and k3 becomes larger than k1.


Ans. (3)


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5)�� Which reaction will dominate (take place the fastest) at moderate temperatures?


At moderate temperatures

Ans. (1)

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6)�� Which reaction will take place the fastest at low temperatures?

At low temperature (1/T) is larger.

Ans. (4)

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7)�� Which reactions will have the same rate of reaction at a given temperature?

����� Ans. The rate will be the same when the lines cross.

����� a. (1) and (3)

����� b. (2) and (3)

����� c. (1) and (4)

����� d. (2) and (4)

����� e. (3) and (4)

The activation energy is a measure of the minimum energy a that the reacting molecules must have in order for the reaction to occur.

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