SSG 1
Sequential Csp3-H Arylation and Olefination: Total Synthesis of the Proposed Structure of Pipercyclobutanamide A
These comic book superheroes will do their best to explain these difficult syntheses to you!
Gutekunst, W.R.; Gianatassio, R.; Baran, P. S. Agnew. Chem. Int. Ed. 2012, 51, 7507-7510.